Sodium Erythorbate E316 CAS. No. 6381-77-7 Sodium Isoascorbate and Sodium D-Isoascorbate

• CAS No.: 6381-77-7
• Formula: C6h7 Nao6.H2O
• EINECS: 228-973-9
• Packaging Material: Paper
• Storage Method: Normal
• Shelf Life: >12 Months
• Model NO.: E316
• Type: Food
• Resource: Chemosynthesis
• Store: Kept in a Light-Proof, Well-Closed, Dry and Cool P
• En. No.: E316
• Molecular Weight: 216.12
• Delivery: 15days
• Loading Port: Qingdao
• Loading Port 2: Shanghia
• Transport Package: 25kg/Caron
• Specification: FCC
• Trademark: JK
• Origin: China
• HS Code: 293220
• Production Capacity: 1000mt/Month

Product Description

Sodium Erythorbate
Description:
CAS NO: 6381-77-7
Other Name: Sodium D-isoascorbate, Erythorbic acid, d-sodium erythorbate
EINECS: 228-973-9
Molecular Formula: C6H7NaO6
Molecular weight: 198.1059
Sodium Erythorbate is White or slightly yellow white crystal granular or powder, odorless, has little salt odor, the melting point is over 200º C, it is rather stable when exposed to the air in drying condition, but in the water solution, when there is air, metal, heat and light, the oxidation, when there is air, metal, heat and light, the oxidation will occur. It easily dissolves in water, 16g/mlat normal temperature, hardly dissolves in ethanol, the PHvalue of 5% water solution is 5.5-8.0
Application:
Sodium Erythorbate is mainly used in food industry as food antioxidant, also used in steel industry, petrochemical industry, medication indusstry and cosmetic industry.
Packing:
25kg/carton or 25kg/bag, 20mts on pallet/20'gp; 22 mts without pallet/20'gp

Use:
1) keep the color, natural flavor of foods and lengthen its storage without any toxic and side effects.
2) they are used in meat processing, fruits, vegetable, tin and jam etc.
3) they are used in drinks, such as beer, grape wine, soft drink, fruit tea and fruit juice etc.

Characteristics	White ODORLESS, crystalLINE POWDER OR GRANULES
identification	Positive reaction
CONTENT	98.0~100.5%
specific rotation	+95.5° ~+ 98.0°
Heavy Metals As Pb	≤10PPM
loss on drying	≤0.25%
ph	5.5~8.0
OXALATES	PASS TEST
LEad Pb	≤5ppm
As	≤3ppm
Clarity	Pass Test
Mercury	≤1ppm
GMO	Free

 

Sodium erythorbate Basic information

Identification test Content analysis Toxicity Usage limit Standard for Allowable Maximum Residue and amount of Food Additives Chemical properties Uses Preparation

Product Name:	Sodium erythorbate
Synonyms:	kanghuaixuesuanna;sodium D-isoascorbate,erythorbic acid;neo-cebitate;ozoban;sodiumd-erythro-3-oxohexonatelactone;sodiumenolatemonohydrate;ISOASCORBIC ACID SODIUM SALT;ERYTHORBIC ACID SODIUM SALT
CAS:	6381-77-7
MF:	C6H7NaO6
MW:	198.11
EINECS:	228-973-9
Product Categories:	Antioxidant;Biochemistry;Vitamin Derivatives;Vitamins;Food additive;Inhibitors
Mol File:	6381-77-7.mol

Sodium erythorbate Chemical Properties

Melting point	154-164°C (decomposes)
alpha	97 º (c=1,DMF)
refractive index	97 ° (C=10, H2O)
form	solid
CAS DataBase Reference	6381-77-7(CAS DataBase Reference)
EPA Substance Registry System	Sodium erythorbate (6381-77-7)

Safety Information

RTECS	MP8910000
Hazardous Substances Data	6381-77-7(Hazardous Substances Data)

MSDS Information

Provider	Language
D-Sodium isoascorbiate	English

Sodium erythorbate Usage And Synthesis

Identification test	Solubility: it is easily soluble in water; extremely difficult to dissolve in ethanol. It can be measured according to the OT-42 method. Take 2 ml of 2.0% sample solution; add 2 mL of water, 0.1 g sodium bicarbonate and 0.02 g of ferrous sulfate. Stand after shaking. At this time, it should exhibit dark purple color while addition of 5 mL of dilute sulfuric acid test solution (TS-241) will make the color disappeared. The burning residue of the sample was dissolved by the water and subject to (TS-2) acidification, and if necessary, subject to filtration. Addition of uranyl zinc acetate test solution (TS-253) should produce yellow crystalline precipitate. The aqueous solution of the sample allows the discoloration of the 2, 6-dichloroindophenol test solution (TS-84).
Content analysis	0.400 g of the sample pre-dried in a vacuum desiccator (sulfuric acid) for 24 hours was dissolved in a mixed solution consisting of 100 ml of de-carbonated water and 25 ml of dilute sulfuric acid solution (TS-241). Add a few drops of starch solution (TS-235) and immediately titrate with 0.1mol/L iodine solution titration. Each mL of 0.1 mol/L iodine solution was equivalent to 10.807 mg of sodium erythorbate (C6H7O6Na? H2O).
Toxicity	ADI is not subject to any special provision (FAO/WHO, 2001). LD50} 15.3 g/kg (mouse, orally).
Usage limit	GB 2760-2001 (g/kg): beer 0.04; wine, fruit and vegetable juice drinks, 0.15. Canned fruits and vegetables, canned meat, jam, frozen fish, 1.0 (all based on ascorbic acid).  FAO/WHO (1984): luncheon meat, boiled forelegs, cooked ham, cooked minced meat, 500mg/kg (single usage amount or combined amount with ascorbic acid, ascorbic acid and its salts in ascorbic acid).
Standard for Allowable Maximum Residue and amount of Food Additives	Name of additive Food allowed to use it as additives Function of additivesallowable usage (g/kg) Sodium Isoascorbate Eight-treasure porridge Anti-oxidants 1.0 Sodium Isoascorbate Soy sauce, vinegar, sauce, liquid compound seasoning Anti-oxidants 1.0 Sodium Isoascorbate Tea and coffee drinks Anti-oxidants 0.5
Chemical properties	It appears as white to yellow-white crystalline powder or granules. It is almost odorless, slightly salty. In the dry state, it is quite stable in the air. However in solution, it will deteriorate in the presence of air, trace metals, heat and light. The melting point is above 200 ºC (decomposition). It is soluble in water (17g/100m1) but almost insoluble in ethanol. The pH of the 2% aqueous solution was 5.5 to 8.0.
Uses	It is antioxidant and antiseptic. Sodium Isoascorbate is a water-soluble antioxidant which is widely used in China and abroad. Its antioxidant property is significantly stronger than vitamin C. Its price is cheap as well. China provides that it can be used for all types of canned, jam and frozen fish with the maximum usage amount of 1.0g/kg; It can be used for meat with the maximum usage amount being 0.5g/kg (to ascorbic acid dollars); can be used for wine and fruit juice drinks with the largest usage amount being 0.15g/kg; can also be used for beer with the maximum usage amount being 0.04g/kg. For food antioxidants, preservatives and coloring agent
Preparation	It is produced through using D-glucose fermentation of Pseudomonas fluorescens Kl005 or Arthrobacter globiformis K1022 to produce 2-keto-D-gluconic acid (or calcium salt), followed by being esterified, transformed and refined. The composition of the fermentation medium is: glucose: 18; yeast extract 0.3; K2HPO4 ? 3H2O: 0.05; KH2PO4: 0.05; MgSO4 ? 7H2O: 0.025,;CaCO:34.5. The fermentation temperature is controlled at 30~35 ºC, the fermentation period is 30h, and the fermentation conversion ratio (%) is 79.9%. The fermentation broth is supplemented with sulfate and activated carbon for acidification and decoloring, followed by pressurized filtrate to obtain the clean liquid with a yield of 96.6%. The purified fermentation broth was concentrated by decompression, and methanol and sulfuric acid were added for refluxed esterification of 5h, followed by frozen and centrifuged filtering to obtain methyl ester with a yield of 82.1%. The methyl ester was transformed with basic methanol solution under refluxing conditions, and the product was further frozen and crystallized to dryness to obtain the crude product of D-isoascorbic acid. The conversion yield was 87.3%, and it was dissolved in hot water and decolorized with activated carbon. The filtrate is pressurized filtrated and the supernatant liquid is frozen, crystallized, centrifugalized, washed and vacuum dried to obtain finished product.  The mother liquid is recovered and the yield is 88.0%.
Chemical Properties	WHITE CRYSTALLINE POWDER
Uses	Antioxidant and preservative.
Uses	Sodium Erythorbate is an antioxidant that is the sodium salt of erythorbic acid. in the dry crystal state it is nonreactive, but in water solution it readily reacts with atmospheric oxygen and other oxidiz- ing agents, a property that makes it valuable as an antioxidant. during preparation, a minimal amount of air should be incorpo- rated and it should be stored at a cool temperature. it has a solubility of 15 g in 100 ml of water at 25°c. on a comparative basis, 1.09 parts of sodium erythorbate are equivalent to 1 part of sodium ascor- bate; 1.23 parts of sodium erythorbate are equivalent to 1 part ery- thorbic acid. it functions to control oxidative color and flavor deterioration in a variety of foods. in meat curing, it controls and accelerates the nitrite curing reaction and maintains the color brightness. it is used in frankfurters, bologna, and cured meats and is occasionally used in beverages, baked goods, and potato salad. it is also termed sodium isoascorbate.
General Description	Almost odorless fluffy, white to off-white crystalline powder. Used as an antioxidant and preservative.
Air & Water Reactions	Water soluble.
Reactivity Profile	Sodium erythorbate may be sensitive to prolonged exposure to light. Incompatible with strong oxidizing agents .
Fire Hazard	Flash point data for Sodium erythorbate are not available; however, Sodium erythorbate is probably combustible.

Sodium erythorbate Preparation Products And Raw materials

Preparation Products	L(+)-Ascorbic acid-->D-Isoascorbic acid
Raw materials	Sodium hydroxide-->Methanol-->D(+)-Glucose-->Starch-->Activated carbon,decolor-->Gluconic acid-->5 KG YEAST EXTRACT SERVABACTERPOWDER-->Zinc silicate-->Calcium oxalate

Packing and transportation:

1.Packing:
25kg/ carton or 25kg/bag, or per your requirement.
18mt/20'FCL
2.Storage:
The resin should be stored in a drafty, dry warehouse and away from fire and direct sunlight. It should not be piled up in the open air.
3.Transportation:
During transportation, the product should not be exposed to strong sunlight or rain and should not be transported together with sand, soil, scrap metal, coal or glass. Transportation together with toxic, corrosive and flammable substance is strictly prohibited.